Issue 50, 2018

PET-RAFT polymerisation: towards green and precision polymer manufacturing

Abstract

The necessity of sustainable development in the chemical industry has continuously drawn attention to find safe, environmentally friendly and atom-economic chemical processes, which is defined in the 12 principles of green chemistry. Merging photoredox catalysis and reversible addition–fragmentation chain transfer (RAFT) polymerisation, the photoinduced electron/energy transfer (PET)-RAFT process has opened up a new way of performing reversible deactivation radical polymerisation for well-defined polymer synthesis using light as an external stimulus. While providing an increased level of control (spatiotemporal, wavelength, and intensity control) over the polymerisation, PET-RAFT has many attractive attributes (abundant catalyst availability, catalyst recyclability, selectivity and oxygen tolerance) to be green and sustainable, which is intriguing for precision polymer manufacturing in industry.

Graphical abstract: PET-RAFT polymerisation: towards green and precision polymer manufacturing

Article information

Article type
Feature Article
Submitted
07 apr 2018
Accepted
10 máj 2018
First published
10 máj 2018

Chem. Commun., 2018,54, 6591-6606

Author version available

PET-RAFT polymerisation: towards green and precision polymer manufacturing

J. Phommalysack-Lovan, Y. Chu, C. Boyer and J. Xu, Chem. Commun., 2018, 54, 6591 DOI: 10.1039/C8CC02783H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements