Issue 16, 2017

Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

Abstract

Reduction of a wide range of aldehydes and ketones with catalytic amounts of titanocene borohydride in concert with a stoichiometric poly(methylhydrosiloxane) (PMHS) reductant is reported. Preliminary mechanistic studies demonstrate that the reaction is mediated by a reactive titanocene(III) complex, whose oxidation state remains constant throughout the reaction.

Graphical abstract: Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

Supplementary files

Article information

Article type
Paper
Submitted
31 máj 2017
Accepted
01 júl 2017
First published
03 júl 2017

Catal. Sci. Technol., 2017,7, 3469-3473

Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

G. D. Fianu, K. C. Schipper and R. A. Flowers II, Catal. Sci. Technol., 2017, 7, 3469 DOI: 10.1039/C7CY01088E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements