Chiral supramolecular organization and cooperativity in DNA-templated assemblies of ZnII–chromophore complexes

Jenifer Rubio-Magnieto; Mohit Kumar; Patrick Brocorens; Julien Idé; Subi J. George; Roberto Lazzaroni; Mathieu Surin

doi:10.1039/C6CC07414F

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Chiral supramolecular organization and cooperativity in DNA-templated assemblies of Zn^II–chromophore complexes†

Jenifer Rubio-Magnieto,^a Mohit Kumar,^b Patrick Brocorens,^a Julien Idé,^a Subi J. George,*^b Roberto Lazzaroni*^a and Mathieu Surin*^a

Author affiliations

* Corresponding authors

^a Laboratory for Chemistry of Novel Materials, Center for Innovation in Materials and Polymers, University of Mons – UMONS, 20 Place du Parc, B-7000 Mons, Belgium
E-mail: mathieu.surin@umons.ac.be, roberto.lazzaroni@umons.ac.be

^b Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, India
E-mail: george@jncasr.ac.in

Abstract

Templated cooperative binding induced assembly of chromophores is achieved via interactions between Zn-complexes and the DNA phosphodiester backbone. The chromophores are organized in left-handed (M)-helices via double-zipper assembly with the DNA templates.

This article is part of the themed collections: Suprabiomolecular Chemistry and Chirality at the nanoscale

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Article information

DOI: https://doi.org/10.1039/C6CC07414F
Article type: Communication
Submitted: 11 sep 2016
Accepted: 03 nov 2016
First published: 03 nov 2016

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Chem. Commun., 2016,52, 13873-13876

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Chiral supramolecular organization and cooperativity in DNA-templated assemblies of Zn^II–chromophore complexes

J. Rubio-Magnieto, M. Kumar, P. Brocorens, J. Idé, S. J. George, R. Lazzaroni and M. Surin, Chem. Commun., 2016, 52, 13873 DOI: 10.1039/C6CC07414F

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