Issue 42, 2015

Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

Abstract

This paper describes the pyrolysis of pyridinedicarboxylate-containing Zn-based metal–organic frameworks (MOFs) to form nanoporous carbons with accessible N dopants to adsorb CO2. The optimal materials were synthesized using N-heterocycle additives to control the amount of coordinated DMF in the base MOF structure, thereby increasing its thermal stability prior to pyrolysis.

Graphical abstract: Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

Supplementary files

Article information

Article type
Communication
Submitted
28 apr 2015
Accepted
12 jún 2015
First published
12 jún 2015

CrystEngComm, 2015,17, 8015-8020

Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

J. Kim, A. G. Oliver and J. C. Hicks, CrystEngComm, 2015, 17, 8015 DOI: 10.1039/C5CE00828J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements