Issue 2, 2015

Fabrication and non-covalent modification of highly oriented thin films of a zeolite-like metal–organic framework (ZMOF) with rho topology

Abstract

Here we report the fabrication of the first thin film of a zeolite-like metal–organic framework (ZMOF) with rho topology (rho-ZMOF-1, ([In48(HImDC)96]48−)n) in a highly oriented fashion on a gold-functionalized substrate. The oriented rho-ZMOF-1 film was functionalized by non-covalent modification via post-synthetic exchange of different probe molecules, such as acridine yellow, methylene blue, and Nile red. In addition, encapsulation of a porphyrin moiety was achieved via in situ synthesis and construction of the rho-ZMOF. Adsorption kinetics of volatile organic compounds on rho-ZMOF-1 thin films was also investigated. This study suggests that rho-ZMOF-1 thin films can be regarded as a promising platform for various applications such as sensing and catalysis.

Graphical abstract: Fabrication and non-covalent modification of highly oriented thin films of a zeolite-like metal–organic framework (ZMOF) with rho topology

Article information

Article type
Communication
Submitted
08 júl 2014
Accepted
11 sep 2014
First published
12 sep 2014

CrystEngComm, 2015,17, 290-294

Fabrication and non-covalent modification of highly oriented thin films of a zeolite-like metal–organic framework (ZMOF) with rho topology

O. Shekhah, A. Cadiau and M. Eddaoudi, CrystEngComm, 2015, 17, 290 DOI: 10.1039/C4CE01402B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements