Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption

Weibin Liang; Ravichandar Babarao; Tamara L. Church; Deanna M. D'Alessandro

doi:10.1039/C5CC02539G

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Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO₂ adsorption†

Weibin Liang,^a Ravichandar Babarao,^b Tamara L. Church^a and Deanna M. D'Alessandro*^a

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* Corresponding authors

^a School of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia
E-mail: deanna.dalessandro@sydney.edu.au

^b Manufacturing Flagship CSIRO, Private Bag 33, Clayton South MDC, Victoria 3169, Australia

Abstract

A combined experimental and computational study has revealed the interplay between the framework pore size and functionality on the CO₂ adsorption performance of zirconium-based MIL-140 frameworks. The CO₂–sorbent interactions were markedly influenced by pore-confinement effects which arise from the π-stacked arrangement of the ligands within the framework backbone.

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Article information

DOI: https://doi.org/10.1039/C5CC02539G
Article type: Communication
Submitted: 27 mar 2015
Accepted: 07 jún 2015
First published: 08 jún 2015

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Chem. Commun., 2015,51, 11286-11289

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Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO₂ adsorption

W. Liang, R. Babarao, T. L. Church and D. M. D'Alessandro, Chem. Commun., 2015, 51, 11286 DOI: 10.1039/C5CC02539G

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