Issue 29, 2013
From the journal:

Chemical Communications

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions†‡

Ganesh Majji,a   Srimanta Guin,a   Anupal Gogoi,a   Saroj Kumar Routa  and  Bhisma K. Patel*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, India
E-mail: patel@iitg.ernet.in
Fax: +91-3612690762

Abstract

An efficient metal free protocol has been developed for the synthesis of benzylic esters via a cross dehydrogenative coupling (CDC) involving alkylbenzene(s) as a self- or as a cross-coupling partner(s) via the intermediacy of Ar–COOH and the benzylic carbocation obtained from the other half of the alkylbenzene; both symmetrical as well as unsymmetrical esters can be prepared using Bu4NI and TBHP.

Graphical abstract: Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC40832A
Article type
Communication
Submitted
31 jan 2013
Accepted
25 feb 2013
First published
25 feb 2013

Chem. Commun., 2013,49, 3031-3033

Permissions

Request permissions

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

G. Majji, S. Guin, A. Gogoi, S. K. Rout and B. K. Patel, Chem. Commun., 2013, 49, 3031 DOI: 10.1039/C3CC40832A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements