Issue 19, 2012
From the journal:

Chemical Communications

Synthesis of a green [60]fullerene derivative through cage-opening reactions†‡

Shuming Liu,abd   Changqi Zhang,ac   Xiang Xie,ac   Yuming Yu,ab   Zhifei Dai,ac   Yuanhua Shao,ac   Liangbing Gan*abc  and  Yuliang Liab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
E-mail: gan@pku.edu.cn

b CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

c Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

d Department of Chemistry, Handan College 056005, China

Abstract

Open-cage derivative C60(O)4(OH)2(NC6H4tBu)2 reacts with ICl to form a Baeyer–Villiger type product, which yields an intense green product upon treatment with HI.

Graphical abstract: Synthesis of a green [60]fullerene derivative through cage-opening reactions

  • This article is part of the themed collection: Aromaticity
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Article information

DOI
https://doi.org/10.1039/C2CC17164C
Article type
Communication
Submitted
18 nov 2011
Accepted
06 jan 2012
First published
10 jan 2012

Chem. Commun., 2012,48, 2531-2533

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Synthesis of a green [60]fullerene derivative through cage-opening reactions

S. Liu, C. Zhang, X. Xie, Y. Yu, Z. Dai, Y. Shao, L. Gan and Y. Li, Chem. Commun., 2012, 48, 2531 DOI: 10.1039/C2CC17164C

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