Issue 15, 2011
From the journal:

Chemical Communications

Templated dynamic cryptophane formation in water†‡

Cécile Givelet,a   Junling Sun,a   Di Xu,a   Thomas J. Emge,a   Ashwini Dhoktea  and  Ralf Warmuth*a  

* Corresponding authors

a Rutgers, The State University of New Jersey, Department of Chemistry and Chemical Biology, 610 Taylor Road, Piscataway, USA
E-mail: warmuth@rutgers.edu
Fax: +1 732-4455312
Tel: +1 732-4458432

Abstract

Several dynamic hexaimine cryptophanes, that are built up from two triformylcyclotribenzylene cavitands and three diamino linkers and spontaneously assemble in water in the presence of a suitable templating guest, are reported. X-ray structure, kinetics and thermodynamics of assembly and molecular recognition properties are discussed.

Graphical abstract: Templated dynamic cryptophane formation in water

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Article information

DOI
https://doi.org/10.1039/C1CC10510H
Article type
Communication
Submitted
26 jan 2011
Accepted
16 feb 2011
First published
11 mar 2011

Chem. Commun., 2011,47, 4511-4513

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Templated dynamic cryptophane formation in water

C. Givelet, J. Sun, D. Xu, T. J. Emge, A. Dhokte and R. Warmuth, Chem. Commun., 2011, 47, 4511 DOI: 10.1039/C1CC10510H

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