Issue 12, 2003

Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

Abstract

Trimethylsilylselenoferrocene 1 has been prepared in good yield. The reactive silyl group on 1 is used as a driving force for the synthesis [Cl4Cd42-Se(C5H4)Fe(C5H5)}6]2− 2, a Cd4Se6 adamantoid cluster with six surface ferrocenyl groups.

Graphical abstract: Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

Supplementary files

Article information

Article type
Communication
Submitted
12 mar 2003
Accepted
15 apr 2003
First published
13 máj 2003

Chem. Commun., 2003, 1398-1399

Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

T. P. Lebold, D. L. B. Stringle, M. S. Workentin and J. F. Corrigan, Chem. Commun., 2003, 1398 DOI: 10.1039/B302829A

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