Co-condensation of hafnium or zirconium atoms from an electron-gun furnace with arenes and trimethyl-phosphine gives good yields of the compounds [M(η-arene)2(PMe3)], M = Hf or Zr.
F. G. N. Cloke and M. L. H. Green, J. Chem. Soc., Chem. Commun., 1979, 127 DOI: 10.1039/C39790000127
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