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Chemical Communications

Stepwise selective crystallization of Fe and Dy complexes from a Fe/Nd/Dy mixture: separation despite charge and solubility similarity

Natsuki Hasegawa,   Akiho Yanai,   Hinako Masaki,   Akira Kirishima,   Ryo Tsunashima  and  Atsuko Masuya-Suzuki  

Abstract

Selective crystallization of charge-identical trenSal complexes enabled stepwise separation of Fe, Nd, and Dy. Remarkably, high selectivity emerged under controlled-base conditions, allowing separation even between species with similar solubilities. This study demonstrates a new approach for f/f and f/d metal separation based on controlled crystallization behavior.

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DOI
https://doi.org/10.1039/D5CC03074A
Article type
Communication
Submitted
30 May 2025
Accepted
29 Sep 2025
First published
30 Sep 2025

Chem. Commun., 2025, Accepted Manuscript

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Stepwise selective crystallization of Fe and Dy complexes from a Fe/Nd/Dy mixture: separation despite charge and solubility similarity

N. Hasegawa, A. Yanai, H. Masaki, A. Kirishima, R. Tsunashima and A. Masuya-Suzuki, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC03074A

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