Abstract
Atomically precise noble metal nanoclusters (NCs) are molecular materials known for their precise composition, electronic structure, and unique optical properties, exhibiting chemical reactivity. Herein, we demonstrated a simple one-pot method for fabricating self-assembled Ag–Au bimetallic mesostructures using a reaction between 2-phenylethanethiol (PET)-protected atomically precise gold NCs and colloidal silver nanoparticles (Ag NPs) in a tunable reaction microenvironment. The reaction carried out in toluene at 45 °C with constant stirring at 250 revolutions per minute (RPM) yielded a thermally stable, micron-sized cuboidal mesocrystals of self-assembled AgAu@PET nanocrystals. However, the reaction in dichloromethane at room temperature with constant stirring at 250 RPM resulted in a self-assembled mesostructure of randomly close-packed AgAu@PET NPs. Using a host of experimental techniques, including optical and electron microscopy, optical absorption spectroscopy, and light scattering, we studied the nucleation and growth processes. Our findings highlight a strategy to utilize precision and plasmonic NP chemistry in tailored microenvironments, leading to customizable bimetallic hybrid three-dimensional nanomaterials with potential applications.
- This article is part of the themed collection: Metal nanoclusters