Topological control in paddlewheel metal-organic cages via ligand length variation

Abstract

Varying the length of phenanthrene-derived ligands switches the selective assembly of MIInLn metal-organic cages (MOCs, n = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu2 and Rh2 paddlewheel MOCs, and supported by solution, solid-state and computational analysis.

Supplementary files

Article information

Article type
Communication
Submitted
26 júl 2024
Accepted
25 sep 2024
First published
26 sep 2024

Chem. Commun., 2024, Accepted Manuscript

Topological control in paddlewheel metal-organic cages via ligand length variation

S. Tsoukatos, A. Maibam, R. Babarao and W. Bloch, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC03769C

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