Construction of a stable radical hydrogen-bonded metal–organic framework with functionalized tetrathiafulvalene linkers†
Abstract
A stable two-dimensional radical hydrogen-bonded metal–organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H4TTFTB) linker and Cd2+ ions, exhibits a high electrical conductivity of 4.1 × 10−4 S m−1 and excellent photothermal conversion with a temperature increase of 137 °C in 15 s under the irradiation of a 0.7 W cm−2 808 nm laser.
- This article is part of the themed collection: Emerging Trends in MOFs