Issue 8, 2023

Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

Abstract

Post synthetically-modified UiO-66-NH2 with a molecular cobaloxime [Co(DMG)2Cl2] (DMG = dimethylglyoxime) catalyst displays excellent photo-(404 μmol g−1 h−1) and electrocatalytic H2 evolution activity in an aqueous solution. Several analytical and spectroscopic methods, including femtosecond transient absorption spectroscopy and DFT, revealed the unique interaction between cobaloxime and the MOF leading to enhanced catalytic activity.

Graphical abstract: Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

Supplementary files

Article information

Article type
Communication
Submitted
07 apr 2023
Accepted
19 jún 2023
First published
19 jún 2023
This article is Open Access
Creative Commons BY-NC license

Energy Adv., 2023,2, 1116-1121

Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

S. Sk, S. P. Shelake, D. Dolui, S. Karim, R. Ghosh, M. V. Jyothirmai, A. V. S. Sainath, U. Pal and A. Dutta, Energy Adv., 2023, 2, 1116 DOI: 10.1039/D3YA00151B

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements