Synthesis, structure, and application of boron-containing macrocycles

Abstract

In recent years, boron-containing macrocycles have received considerable research interest. This review summarizes the reported examples of boron macrocycles containing alkyl/aryl borane units, B–O bonds, and B–N bonds. The synthesis and structure of these macrocyclic compounds are highlighted. Moreover, further applications of these boron-containing macrocycles in anion sensing, host–guest interactions, and supramolecular catalysis are briefly introduced.