Issue 13, 2022

A highly transparent and photothermal composite coating for effective anti-/de-icing of glass surfaces

Abstract

Anti-/de-icing of glass surfaces is of great importance in present daily life. The long-standing challenge in this field is largely due to the lack of stable multifunctional coatings that can be conveniently and economically constructed on the glass surface, and more importantly, are capable of retaining the original transparency of glass ranging from the visible to the near infrared spectrum. Herein, a direct spraying sol method on the glass surface to prepare a highly transparent and photothermal composite coating is reported. Such multifunctional coating of Cu7S4 nanoparticles/organo-silicone sols has displayed a good photothermal conversion property and hydrophobic property and therefore yields excellent anti-icing and self-melting ice properties. The condensation time of water droplets can be extended to 86 s even at −10 °C, which is 3.42 times delayed relative to ordinary blank glass. And the adhesion strength of ice is largely reduced to 72 KPa, which is as low as ∼1/3 that of ordinary glass. Meanwhile, the subcooling of adhering droplets is reduced to −12 °C under one solar illumination condition and exhibits a rapid de-icing capability. More impressively, the prepared functional coating glass shows an outstanding transmittance of more than 75% in the visible region, while it is over the minimum glass transmittance limit allowed by Safety Standards for Glass (GB9656-2016, China). In addition, the multifunctional photothermal glass coating exhibits good physical/chemical stability, which facilitates the long-term application of the coating in different environments.

Graphical abstract: A highly transparent and photothermal composite coating for effective anti-/de-icing of glass surfaces

Supplementary files

Article information

Article type
Paper
Submitted
11 mar 2022
Accepted
10 máj 2022
First published
11 máj 2022
This article is Open Access
Creative Commons BY-NC license

Nanoscale Adv., 2022,4, 2884-2892

A highly transparent and photothermal composite coating for effective anti-/de-icing of glass surfaces

W. Guo, C. Liu, N. Li, M. Xi, Y. Che, C. Jiang, S. Zhang and Z. Wang, Nanoscale Adv., 2022, 4, 2884 DOI: 10.1039/D2NA00151A

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