Issue 67, 2022

Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

Abstract

The cubic SBU Ni8X6L6 (X = OH/H2O, L = ligand) is of great interest due to its stability and potential applications when integrated in MOFs. Here, we investigate by detailed DRIFTS measurements and exchange reactions whether it is found to be neutral in MOFs, as previously assumed in the literature, or whether it can show anionic character, as observed in complexes.

Graphical abstract: Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

Supplementary files

Article information

Article type
Communication
Submitted
30 máj 2022
Accepted
26 júl 2022
First published
26 júl 2022

Chem. Commun., 2022,58, 9349-9352

Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

R. Freund, A. Kalytta-Mewes, M. Kraft and D. Volkmer, Chem. Commun., 2022, 58, 9349 DOI: 10.1039/D2CC03016K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements