Issue 75, 2022

The importance of crystal size for breathing kinetics in MIL-53(Al)

Abstract

Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al).

Graphical abstract: The importance of crystal size for breathing kinetics in MIL-53(Al)

Supplementary files

Article information

Article type
Communication
Submitted
10 máj 2022
Accepted
29 júl 2022
First published
22 aug 2022

Chem. Commun., 2022,58, 10492-10495

The importance of crystal size for breathing kinetics in MIL-53(Al)

V. Bon, N. Busov, I. Senkovska, N. Bönisch, L. Abylgazina, A. Khadiev, D. Novikov and S. Kaskel, Chem. Commun., 2022, 58, 10492 DOI: 10.1039/D2CC02662G

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