Ni/Co bimetallic organic framework nanosheet assemblies for high-performance electrochemical energy storage†
Abstract
Nickel–cobalt organic framework (denoted as NiCo-MOF) nanosheet assemblies are prepared through a controllable one-pot hydrothermal synthesis procedure at 150 °C. The as-prepared samples are directly employed as electrode materials for electrochemical energy storage (EES), and exhibit excellent electrochemical performance. Among these samples, NiCo-MOF-1 displays a high capacity of 100.18 mA h g−1 (901.60 F g−1), and obtains a capacity retention of 81.00% over 3000 cycles at 5 A g−1. Likewise, in an aqueous device, NiCo-MOF-1//AC delivers a discharge capacity of 83.75 mA h g−1, and also exhibits a good cycling life (74.14% retention after 3000 cycles). These results demonstrate that multilayer NiCo-MOF nanosheet assemblies are potential electrode materials for EES.
- This article is part of the themed collections: Advanced Nanomaterials for Energy Conversion and Storage, Nanoscale 2021 Lunar New Year Collection and 2020 Nanoscale HOT Article Collection