Issue 19, 2020

Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Abstract

Herein, novel photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O is reported. The protocol was compatible with a variety of functionalities, including halogen, alkoxy, cyano, sulfonyl, trimethylsilyl, trifluoromethoxy, alkyl, hydroxyl, free acid, amide, and heteroaromatic rings. A wide range of deuterated products were obtained in good yields with a high level of deuteration. This method provides a green and practical pathway to synthesize deuterium labelled compounds under mild conditions.

Graphical abstract: Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Supplementary files

Article information

Article type
Communication
Submitted
15 máj 2020
Accepted
01 júl 2020
First published
10 júl 2020

Green Chem., 2020,22, 6323-6327

Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Y. Lang, X. Peng, C. Li and H. Zeng, Green Chem., 2020, 22, 6323 DOI: 10.1039/D0GC01649G

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