The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Thomas Dumas; Dominique Guillaumont; Philippe Moisy; David K. Shuh; Tolek Tyliszczak; Pier Lorenzo Solari; Christophe Den Auwer

doi:10.1039/C8CC05176C

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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy†

Thomas Dumas,

*^a Dominique Guillaumont,

^a Philippe Moisy,

^a David K. Shuh,

^b Tolek Tyliszczak,^c Pier Lorenzo Solari^d and Christophe Den Auwer

^ae

Author affiliations

* Corresponding authors

^a CEA, Nuclear Energy Division, Radiochemistry and Process Department, 30207 Bagnols-sur-Cèze, France
E-mail: thomas.dumas@cea.fr

^b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

^c Advanced Light Source Division, Lawrence Berkeley National Laboratory, LBNL, Berkeley, CA 94720, USA

^d Synchrotron SOLEILL'Orme des Merisiers, Saint-Aubin, Gif-sur-Yvette Cedex, France

^e Université Côte d'Azur, CNRS, Institut de Chimie de Nice, UMR 7272, 06108 Nice, France

Abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

This article is part of the themed collection: New molecules and materials from the f-block

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Article information

DOI: https://doi.org/10.1039/C8CC05176C
Article type: Communication
Submitted: 28 jún 2018
Accepted: 25 sep 2018
First published: 25 sep 2018

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Chem. Commun., 2018,54, 12206-12209

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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

T. Dumas, D. Guillaumont, P. Moisy, D. K. Shuh, T. Tyliszczak, P. L. Solari and C. Den Auwer, Chem. Commun., 2018, 54, 12206 DOI: 10.1039/C8CC05176C

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Chemical Communications

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy†

Abstract

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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

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