Issue 32, 2016
From the journal:

Chemical Communications

Halogen bonding between metal centers and halocarbons†

Daniil M. Ivanov,a   Alexander S. Novikov,a   Ivan V. Ananyev,b   Yulia V. Kirinaa  and  Vadim Yu. Kukushkin*a  

* Corresponding authors

a Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab., 7/9, Saint Petersburg, Russian Federation
E-mail: v.kukushkin@spbu.ru

b A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St., 28, Moscow, Russian Federation

Abstract

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C–I⋯η1(Pt) halogen bonding and the bifurcated HI2C–I⋯η2(Pt–Cl) halogen bonding – the latter undergoes the thermally induced reversible HI2C–I⋯η2(Pt–Cl) ⇄ HI2C–I⋯η1(Pt) transformation – were observed and confirmed theoretically.

Graphical abstract: Halogen bonding between metal centers and halocarbons

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Article information

DOI
https://doi.org/10.1039/C6CC01107A
Article type
Communication
Submitted
03 feb 2016
Accepted
16 mar 2016
First published
16 mar 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 5565-5568

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Halogen bonding between metal centers and halocarbons

D. M. Ivanov, A. S. Novikov, I. V. Ananyev, Y. V. Kirina and V. Yu. Kukushkin, Chem. Commun., 2016, 52, 5565 DOI: 10.1039/C6CC01107A

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