A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

Pradip K. Sukul; Purnandhu Bose; Toshiaki Takei; Omar M. Yaghi; Ying He; Myongsoo Lee; Kentaro Tashiro

doi:10.1039/C5CC08973E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly†

Pradip K. Sukul,^a Purnandhu Bose,^a Toshiaki Takei,^a Omar M. Yaghi,^ab Ying He,^c Myongsoo Lee^c and Kentaro Tashiro*^a

Author affiliations

* Corresponding authors

^a International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan
E-mail: TASHIRO.Kentaro@nims.go.jp
Fax: +81-29-860-4706
Tel: +81-29-860-4879

^b Department of Chemistry, University of California–Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley, University of California–Berkeley, Berkeley, California 94720, USA

^c College of Chemistry, Jilin University, Changchun 130-012, China

Abstract

Water-soluble metal–organic complex array 1, bearing Ru(II), Pt(II) and Rh(III) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembly behaviours in aqueous media. NaCl-induced aggregation of 1 at neutral pH was suppressed in phosphate buffered saline containing a mixture of Cl⁻, HPO₄²⁻ and H₂PO₄⁻, which is unconventional for a peptide amphiphile.

This article is part of the themed collection: Celebrating the 2017 RSC Prize and Award Winners

Download options Please wait...

Supplementary files

Supplementary information PDF (6588K)

Article information

DOI: https://doi.org/10.1039/C5CC08973E
Article type: Communication
Submitted: 29 okt 2015
Accepted: 02 nov 2015
First published: 02 nov 2015

Download Citation

Chem. Commun., 2016,52, 1579-1581

Author version available

Download author version (PDF)

Permissions

Request permissions

A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

P. K. Sukul, P. Bose, T. Takei, O. M. Yaghi, Y. He, M. Lee and K. Tashiro, Chem. Commun., 2016, 52, 1579 DOI: 10.1039/C5CC08973E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly†

Abstract

Supplementary files

Article information

Download Citation

Author version available

Permissions

A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

Social activity

Search articles by author

Spotlight

Advertisements