A simple one-pot synthesis of highly fluorescent nitrogen-doped graphene quantum dots for the detection of Cr(vi) in aqueous media

Abstract

A new method for selective determination of Cr(VI) in environmental water samples was developed based on its quenching effect on the fluorescent N-doping graphene quantum dots (N-GQDs). The N-GQDs were synthesized by a simple one-step method using citric acid as the carbon source and ammonia as the nitrogen source with a 65% yield, showing that mass production of the N-GQDs is possible. The obtained N-GQDs with oxygen-rich functional groups exhibited a strong blue emission with a quantum yield of 18.6%, which was 7 times greater than that of graphene quantum dots (GQDs). Due to the selective coordination to Cr(VI), the N-GQDs can be used as a green and facile sensing platform for label-free sensitive and selective detection of Cr(VI) ions in aqueous solution and real water samples. Compared to GQDs, the N-GQDs as a fluorescent probe promises much improved selectivity for sensing of Cr(VI). The N-GQDs fluorescence probe shows a sensitive response to Cr(VI) in a wide concentration range of 0–140 μM with a detection limit of 40 nM. The N-GQDs-based fluorescence method was successfully used to selectively detect Cr(VI), and discriminate it and Cr(III) as well in aqueous samples.