Issue 30, 2014
From the journal:

Chemical Communications

Layered structures and nanosheets of pyrimidinethiolate coordination polymers†

P. J. Beldon,a   S. Tominaka,ab   P. Singh,c   T. Saha Dasgupta,c   E. G. Bithella  and  A. K. Cheetham*a  

* Corresponding authors

a Materials Science & Metallurgy, University of Cambridge, CB3 0FS, UK
E-mail: akc30@cam.ac.uk
Tel: +44 (0)1223 767061

b International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Ibaraki 305-0044, Japan

c S.N. Bose National Centre for Basic Sciences, Block-JD, Salt Lake, Kolkata 700098, India

Abstract

We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.

Graphical abstract: Layered structures and nanosheets of pyrimidinethiolate coordination polymers

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Article information

DOI
https://doi.org/10.1039/C4CC00771A
Article type
Communication
Submitted
28 jan 2014
Accepted
27 feb 2014
First published
27 feb 2014

Chem. Commun., 2014,50, 3955-3957

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Layered structures and nanosheets of pyrimidinethiolate coordination polymers

P. J. Beldon, S. Tominaka, P. Singh, T. Saha Dasgupta, E. G. Bithell and A. K. Cheetham, Chem. Commun., 2014, 50, 3955 DOI: 10.1039/C4CC00771A

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