Issue 65, 2012

Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation§

Abstract

The palladium-catalysed heteroannulation of [60]fullerene with various N-benzyl sulfonamides via C–H bond activation affords [60]fullerene-fused tetrahydroisoquinolines. In the presence of a Brønsted acid [60]fullerene-fused tetrahydroisoquinolines are transformed to [60]fullerene-fused indanes, in which the sulfonamide group can be removed or replaced with an aryl group.

Graphical abstract: Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation

  • This article is part of the themed collection: Aromaticity

Supplementary files

Article information

Article type
Communication
Submitted
31 máj 2012
Accepted
22 jún 2012
First published
09 júl 2012

Chem. Commun., 2012,48, 8132-8134

Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation

Y. Su, Y. Wang and G. Wang, Chem. Commun., 2012, 48, 8132 DOI: 10.1039/C2CC33923D

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