Issue 65, 2012

Relationship of charge to antiaromaticity in bis-fluorenyl dications and fluorenyl monocations: experimental support for theoretical calculations

Abstract

The antiaromaticity of fluorenyl cations is dependent on the magnitude of the charge of the system. Theoretical assessments of antiaromaticity and charge were supported by experimental NMR chemical shifts. Delocalization was related to antiaromaticity, and evaluated through the standard deviation of the charges on carbons of the fluorenyl systems.

Graphical abstract: Relationship of charge to antiaromaticity in bis-fluorenyl dications and fluorenyl monocations: experimental support for theoretical calculations

  • This article is part of the themed collection: Aromaticity

Supplementary files

Article information

Article type
Communication
Submitted
26 máj 2012
Accepted
14 jún 2012
First published
15 jún 2012

Chem. Commun., 2012,48, 8099-8101

Relationship of charge to antiaromaticity in bis-fluorenyl dications and fluorenyl monocations: experimental support for theoretical calculations

N. S. Mills and S. P. McClintock, Chem. Commun., 2012, 48, 8099 DOI: 10.1039/C2CC33799A

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