Issue 62, 2012
From the journal:

Chemical Communications

Water compatibility and organic transformations of organo-Zintl deltahedral clusters†‡

Michael W. Hull*a  and  Slavi C. Sevov*b  

* Corresponding authors

a Department of Chemistry and Physics, Northwest Missouri State University, 800 University Drive, Missouri 64468, Maryville, USA
E-mail: mhull@nwmissouri.edu
Fax: +1 660-562-1188
Tel: +1 660-562-0826

b Department of Chemistry and Biochemistry, University of Notre Dame, Indiana 46556, Notre Dame, USA
E-mail: ssevov@nd.edu
Fax: +1 574-631-6652
Tel: +1 574-631-5891

Abstract

We report the remarkable stability of di-substituted organo-Zintl deltahedral clusters in the presence of water. This has been exploited in a reaction at the organic substituents of the cluster which produces water as a by-product. Also reported are the synthesis, characterization, and crystal structure of [K-krypt]2[Ge9–(CH[double bond, length as m-dash]CH–CH2NH2)2] involved in the reaction.

Graphical abstract: Water compatibility and organic transformations of organo-Zintl deltahedral clusters

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Article information

DOI
https://doi.org/10.1039/C2CC32263C
Article type
Communication
Submitted
28 mar 2012
Accepted
26 apr 2012
First published
27 apr 2012

Chem. Commun., 2012,48, 7720-7722

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Water compatibility and organic transformations of organo-Zintl deltahedral clusters

M. W. Hull and S. C. Sevov, Chem. Commun., 2012, 48, 7720 DOI: 10.1039/C2CC32263C

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