Issue 38, 2012
From the journal:

Chemical Communications

A début for base stabilized monoalkylsilylenes†‡

Ramachandran Azhakar,a   Rajendra S. Ghadwal,*a   Herbert W. Roesky,*a   Hilke Wolfa  and  Dietmar Stalke*a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany
E-mail: hroesky@gwdg.de, rghadwal@uni-goettingen.de, dstalke@chemie.uni-goettingen.de

Abstract

The first base stabilized monoalkylsilylenes LSitBu (2) and LSi[C(SiMe3)3] (3) (L = PhC(NtBu)2) were synthesized by the facile metathesis reactions of LitBu and KC(SiMe3)3 with LSiCl (1). The reaction of LSitBu (2) with N2O afforded the dimer [LSitBu(μ-O)]2 (4) which contains a four-membered Si2O2 ring.

Graphical abstract: A début for base stabilized monoalkylsilylenes

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Article information

DOI
https://doi.org/10.1039/C2CC31041D
Article type
Communication
Submitted
13 feb 2012
Accepted
14 mar 2012
First published
15 mar 2012

Chem. Commun., 2012,48, 4561-4563

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A début for base stabilized monoalkylsilylenes

R. Azhakar, R. S. Ghadwal, H. W. Roesky, H. Wolf and D. Stalke, Chem. Commun., 2012, 48, 4561 DOI: 10.1039/C2CC31041D

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