Issue 21, 2011
From the journal:

Chemical Communications

Reversible anion-templated self-assembly of [2+2] and [3+3] metallomacrocycles containing a new dicopper(i) motif†‡

Emily F. V. Dry,a   Jack K. Clegg,a   Boris Breiner,a   Daniel E. Whitaker,a   Roman Stefak§a  and  Jonathan R. Nitschke*a  

* Corresponding authors

a University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, UK
E-mail: jrn34@cam.ac.uk

Abstract

A new dicopper(I) complex is reported that can be incorporated into extended architectures through multitopic carboxylate linkers; reversible carboxylate templation under pH control led to the formation of [2+2] and [3+3] metallomacrocycles.

Graphical abstract: Reversible anion-templated self-assembly of [2+2] and [3+3] metallomacrocycles containing a new dicopper(i) motif

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Article information

DOI
https://doi.org/10.1039/C1CC11206F
Article type
Communication
Submitted
28 feb 2011
Accepted
23 mar 2011
First published
08 apr 2011

Chem. Commun., 2011,47, 6021-6023

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Reversible anion-templated self-assembly of [2+2] and [3+3] metallomacrocycles containing a new dicopper(I) motif

E. F. V. Dry, J. K. Clegg, B. Breiner, D. E. Whitaker, R. Stefak and J. R. Nitschke, Chem. Commun., 2011, 47, 6021 DOI: 10.1039/C1CC11206F

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