Diazabutadiene complexes of selenium as Se2+ transfer reagents

Jason L. Dutton; Taylor L. Battista; Michael J. Sgro; Paul J. Ragogna

doi:10.1039/B917841D

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Diazabutadiene complexes of selenium as Se²⁺ transfer reagents†

Jason L. Dutton,^a Taylor L. Battista,^a Michael J. Sgro^a and Paul J. Ragogna*^a

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* Corresponding authors

^a Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, Ontario, Canada
E-mail: pragogna@uwo.ca
Fax: +1-519-661-3022
Tel: +1-519-661-2111 ext. 87048

Abstract

Alkyl and aryl substituted diazabutadiene ligands are shown to support a highly electrophilic “Se²⁺” synthon, which can be utilized in ligand exchange reactions to generate Se centred dicationic coordination complexes.

This article is part of the themed collection: Selenium & Tellurium chemistry at the beginning of the 3rd millennium: a celebration of ICCST

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Crystal structure data TXT (85K)

Article information

DOI: https://doi.org/10.1039/B917841D
Article type: Communication
Submitted: 01 sep 2009
Accepted: 02 dec 2009
First published: 23 dec 2009

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Chem. Commun., 2010,46, 1041-1043

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Diazabutadiene complexes of selenium as Se²⁺ transfer reagents

J. L. Dutton, T. L. Battista, M. J. Sgro and P. J. Ragogna, Chem. Commun., 2010, 46, 1041 DOI: 10.1039/B917841D

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