Issue 37, 2009
From the journal:

Chemical Communications

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions†‡

Xiaochen Wang,a   Zhuoyan Lia  and  Michael P. Doyle*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
E-mail: mdoyle3@umd.edu
Fax: +1 301-314-2779
Tel: +1 301-405-1788

Abstract

Lewis bases, including reactant aldehydes, inhibit the rate of conversion for cycloaddition and those, like aldehydes or nitriles, cause a decrease in enantiocontrol due to the Lewis acidity of the activated complex.

Graphical abstract: Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B913019E
Article type
Communication
Submitted
01 júl 2009
Accepted
14 aug 2009
First published
26 aug 2009

Chem. Commun., 2009, 5612-5614

Permissions

Request permissions

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

X. Wang, Z. Li and M. P. Doyle, Chem. Commun., 2009, 5612 DOI: 10.1039/B913019E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements