Israel Oliveira
Cavalcante
a,
Francisco
Simão Neto
b,
Patrick da Silva
Sousa
b,
Francisco Izaias da Silva
Aires
a,
Dayana Nascimento
Dari
a,
Rita Karolinny
Chaves de Lima
a and
José C. S.
dos Santos
*a
aInstituto de Engenharias e Desenvolvimento Sustentável, Universidade da Integração Internacional da Lusofonia Afro-Brasileira, Campus das Auroras, Redenção, CE CEP 62790970, Brazil. E-mail: jcs@unilab.edu.br; Tel: +55(85) 9975-23838
bDepartamento de Engenharia Química, Universidade Federal do Ceará, Campus do Pici, Bloco 709, Fortaleza, CE CEP 60455760, Brazil
First published on 13th December 2023
Considering the interest in innovations in the energy sector and government policies that seek an energy system free of polluting agents, blue hydrogen, whose production takes place through fossil fuels with the capture of CO2, is seen as a way to offer economic opportunities for production with a reduced amount of unwanted by-products. Thus, in blue hydrogen research, the United States leads in the number of publications (16) and the number of citations and H-index, closely followed by England, Norway, and China. However, when considering the number of institutions involved in research in this field, the United Kingdom has a prominent place, the main one being Research Libraries UK (RLUK), with 10 articles published. Also notable is the participation of South Korea in the ranking of active development agencies (8%). Thus, advanced bibliometric analysis techniques were implemented in this study, using the Web of Science website, to understand the cooperative relationships between authors, countries, institutions, and agencies in developing research on blue hydrogen, establishing parameters to understand future trends and the main derived subfields. Thus, it is possible to verify the role of the United States as the primary research center today and to identify which topics involve hydrogen production. Future research will address storage routes due to their relevance in integrating blue hydrogen into the energy matrix.
Sustainability spotlightThe sustainable advancement highlighted in this work on blue hydrogen research demonstrates a significant commitment to the United Nations Sustainable Development Goals (SDGs). By focusing on the production of hydrogen with reduced emissions, the study is in line with SDG 7 (Clean and Affordable Energy), contributing to the global energy transition. Furthermore, by highlighting cooperation between countries and institutions, it promotes SDG 17 (Partnerships and Means of Implementation), fostering international collaboration to address environmental challenges. The research also anticipates future hydrogen storage issues, linking to SDG 9 (Industry, Innovation and Infrastructure) by driving technological advancements. Thus, this study not only advances scientific knowledge, but also stands out as a relevant contribution to a more sustainable future, in line with the principles of the UN 2030 Agenda. |
Before delving into the more specific characteristics of blue hydrogen, a brief explanation of the differences between other classes of this product, such as grey and green, is necessary. To differentiate them, it is required to highlight their production routes, where blue hydrogen is produced from natural gas (methane) in a process called steam reforming that results in the capture and storage of carbon, thus contributing to a reduction in gas emission that worsens the greenhouse effect. Grey hydrogen differs from blue hydrogen as it does not capture carbon, making it a more polluting production route. Finally, green hydrogen is an environmentally friendly production route, as it uses the electrolysis of water generated from energy from renewable sources, such as wind and solar. Therefore, in the process of generating green hydrogen, carbon is not released into the atmosphere.
The production of blue hydrogen is based on carbon capture and storage (CCS),12 a technology that involves capturing the carbon dioxide (CO2) obtained during the hydrogen production process and storing it in geologically safe places, such as underground reservoirs of oil and gas.13 This process begins with natural gas reforming, a chemical reaction that transforms natural gas into hydrogen and carbon dioxide.14 The hydrogen is then separated from the carbon dioxide and purified, and the CO2 is captured and stored securely.15 This technology allows hydrogen to be produced with almost zero carbon emissions, presenting itself as a way to decarbonize the energy matrix.16
While blue hydrogen production could offer a low-carbon option for the industry and other applications, there are also concerns about the high cost involved in producing it.17,18 One of the main challenges is ensuring that this type of hydrogen production is economically viable and competitive with other renewable energy sources.19 In addition, concerns regarding the availability of natural gas sources, the fuel used to produce blue hydrogen, and the feasibility of carbon capture and storage limit its large-scale application.20,21 It is also essential to ensure that blue hydrogen production is environmentally sustainable, as capturing and storing carbon can have significant environmental impacts.22,23 Therefore, it is necessary to carefully evaluate investments in blue hydrogen production and ensure they are viable and sustainable in the long run.24
Thus, the implementation of this category of hydrogen on a commercial scale is still seen as ambitious.25 However, introducing blue hydrogen into the energy system presents favourable parameters.26,27 An organized and equipped infrastructure is essential to efficiently guarantee management from the initial production processes to this fuel's safe storage and distribution.28
On the other hand, this category of hydrogen production offers a solution for reducing greenhouse gas emissions, encouraging the development of new technologies to meet the growing energy demand in the most diverse sectors of the global market.29–31 Thus, the blue hydrogen produced can be used in several applications, such as producing electricity in power plants, transporting vehicles powered by fuel cells, and producing fertilizers and chemical products.32
In addition, we can use blue hydrogen in an integrated manner with other alternative energy sources. This is possible through storage of hydrogen energy, which can be used when wind and solar energy are unavailable.33 Despite offering many benefits, there is still a need for investments in CO2 storage infrastructure, as well as the lack of government policies to encourage the adoption of this technology and its implementation in the world's energy matrix in a more expressive way.34
For this study, bibliometric analysis is a research technique that uses quantitative indicators to assess scientific production in a given area of knowledge.35–37 The objective is to identify patterns and trends in the scientific literature and map the main contributions and authors in a field of study.38–40
Thus, through advanced bibliometric analysis of the Web of Science (WoS) site database, this study proposes to evaluate and present the development of the scientific production process of research aimed at the challenges and opportunities in producing blue hydrogen. Therefore, we seek to understand the current research scenario for this hydrogen category and the future trends in this area. In this way, this analysis focuses on investigating advancements, updates, and trends in improving processes for obtaining this hydrogen category.
This study contributes to the description of available technologies and provides the possibility to evaluate diverse applications of this fuel and explore innovative opportunities for its use in sustainable processes. Consequently, this study offers a solid foundation for future research and represents an important step toward transitioning the industry towards a circular economy in the context of blue hydrogen production.41 In addition, the following questions are sought to be answered:
• RQ1 How has scientific production developed in research on the challenges and prospects of blue hydrogen production?
• RQ2 Who are the main authors in blue hydrogen production research?
• RQ3 What are the main emerging subfields of research on blue hydrogen production in recent literature?
• RQ4 What are the main hotspots used in the literature search?
Fig. 1 Representation of the study methodology search criteria and refinement condition in the WoS database. |
The qualitative data of the publications present in the database and the impact factor (IF) of the productions were taken into account, as well as the category (Q1, Q2, Q3, and Q4) in which each of the journals and articles is inserted since these indices are responsible for presenting the most relevant productions in a given area of knowledge.57–59 In addition, another critical parameter to be considered for this study is the H index, an indicator used to evaluate the scientific production of researchers, research groups, institutions, and countries. It measures the quantity and quality of a researcher's works, considering the number of citations these publications receive.60,61
VOSviewer (https://www.vosviewer.com) was used to build these networks,62 which synthesized the data from scientific productions in the blue hydrogen area. In this way, to relate these categories, analysis techniques can be used to build and present the connections between them. Citation analysis is a technique used in bibliometrics to assess the relevance and impact of a scientific publication and identify relationships between different publications. It is based on counting the number of times an article is cited by other articles.63 However, to analyze co-citations and co-occurrences, the associations between articles, how they are referenced, and the quantity of that occurrence must be kept in mind.64 Furthermore, there is also co-authorship analysis, a technique used to define collaboration relationships between authors.65 For this bibliometric analysis, VOSviewer software was used to perform (i) citation analysis by country/region, (ii) citation analysis by institution, (iii) analysis of co-authorship and co-citation of authors, (iv) journal co-citation analysis, and (v) keyword co-occurrence analysis.
In order to build a visual structure capable of presenting the desired parameters and establishing the correlations between each of them, figures were created in VOSviewer to provide a reliable statistical approach combined with a more transparent and objective presentation of the results obtained. Thus, some graphic representations were developed to visualize these data, such as user nodes, to represent keywords, articles, regions, and institutions, where each node can be distinguished by colour according to the time of occurrence. Furthermore, these nodes' size and position relative to the centre of the map indicate relevance. To display the connections between each of the chosen parameters, some lines connect the nodes, showing how the publications are related to each other, and the thickness of the lines indicates how strong this relationship is, using the total link strength of the connection (TLS) to assess the connection between works quantitatively.66
The CiteSpace Java program, a visualization and analysis tool for bibliometric data to identify trends, patterns, and relationships in large citation datasets, was also used.67 It allows the analysis of citations, co-citations, and co-occurrences of keywords. It also provides resources to identify co-authorship networks and institutions and analyze the geographic distribution of these works.68,69 Based on the information collected, CiteSpace produces interactive charts and maps that help users identify emerging research areas and the prominent researchers and institutions involved in a field of study. That said, through this software, it was possible to perform (i) co-authorship analysis of institutions, (ii) analysis of co-authorship and co-citation of authors, (iii) journal co-citation analysis, (iv) overlapping of journal double maps, and (v) analysis of co-citation of references.
Therefore, the graphical representations built with the help of the VOSviewer and CiteSpace software make it possible to categorize the correlations between the academic data recovered in the Web of Science. The nodes in a map represent the type of study being considered, and their size is defined concerning the number of times it was cited. The connections between nodes represent the strength of collaborations, co-citations, or co-occurrences between studies. In these visualization maps, clusters that refer to a group of highly connected articles through citations can also be observed.
In order to visualize these data for the bibliometric analysis developed here, it is essential to reiterate that different parameter configurations were considered for this study. Some of the main parameters that can be configured in VOSviewer include the source of terms (title, abstract, plus keyword and author keyword), node type (institution, author, cited author, reference or keyword), selection criteria (top 50) and pruning of segmented networks. The CiteSpace software also allows us to adjust the temporal division, where we consider the time interval of publications made between 2012 and 2022. There is also term selection, node type, selection criteria, pruning, and visualization.
Therefore, VOSviewer and CiteSpace were used to analyze the entire database and elaborate correctly directed discussions. In the main text of this study, we present all the results obtained through these advanced bibliometric tools. It is essential to highlight that data analysis through different tools can provide unique and complementary insights into the trends and patterns in a given field of research.
Fig. 2 Global trend of annual publications and citations related to blue hydrogen production research from 2020 to 2023. |
• RQ1 How has scientific production developed in research on the challenges and prospects of blue hydrogen production?
To visualize the distribution of published works, we have a world map (Fig. 3A), created after processing the data using Excel as a tool. It is possible to analyze the density of these publications in each country through colours. In order to present how the distribution of published articles occurred throughout the analyzed period (2012–2023), Fig. 3B shows the contribution of the top 10 most relevant countries in blue hydrogen research, demonstrating the increasing number of articles and other works. For this, the period from 2019 to 2023 was used, as no articles were published in the field of study in previous years. As shown in Fig. 3C, the United States leads scientific production in the field, with 16 articles (18.39%) out of the 87 articles obtained from the database, followed by England with 13 publications (14.94%). Fig. 3D shows the number of citations per country, where the United States has been cited 216 times for these articles, followed by Canada with 201 citations, contributing to 1.242 citations across 24 collaborating countries. Analyzing the H-index of the leading countries through Fig. 3E, it is possible to verify that the United States and England stand out from the others, both presenting an H-index equal to 5.
Regarding the international cooperation among countries, Fig. 4A aims to provide a visualization of co-authorship analysis. Thus, the United States, England, and Canada show a robust collaborative relationship in research in this hydrogen category. As for the information presented in Fig. 4B, the contribution of 24 countries is indicated, considering that each country should have at least one document for analysis in VOSviewer, where each “node” represents the countries that have contributed to the scientific community in recent years. Furthermore, with the visual map presented by the software, it can be observed that Canada has the highest TLS (TLS = 27).
Rank | Institutions | Countries/regions | Count |
---|---|---|---|
1 | Research Libraries UK (RLUK) | United Kingdom | 10 |
2 | SINTEF | Norway | 6 |
3 | N8 Research Partnership | United Kingdom | 4 |
4 | Universidad Politécnica de Madrid | Spain | 4 |
5 | University of Calgary | Canada | 4 |
6 | ETH Zurich | Switzerland | 3 |
7 | Swiss Federal Institutes of Technology Domain | Switzerland | 3 |
8 | University of Manchester | United Kingdom | 3 |
9 | Aarhus University | Denmark | 2 |
10 | Boston University | EUA | 2 |
Funding agencies | Countries/regions | Count | Percentage (%) |
---|---|---|---|
Research Council of Norway | Norway | 4 | 4.59 |
National Research Foundation of Korea | South Korea | 3 | 3.44 |
Qatar National Research Fund (QNRF) | Qatar | 3 | 3.44 |
Spanish Government | Spanish | 3 | 3.44 |
Australian Research Council | Australia | 2 | 2.29 |
Canada First Research Excellence Fund | Canada | 2 | 2.29 |
China Scholarship Council | China | 2 | 2.29 |
European Commission | European Union | 2 | 2.29 |
Korea Institute of Energy Technology Evaluation Planning (KETEP) | South Korea | 2 | 2.29 |
Ministry of Science, ICT and Future Planning, Republic of Korea | South Korea | 2 | 2.29 |
• RQ2 Who are the main authors in blue hydrogen production research?
For the visualization of the top 20 emerging authors in blue hydrogen research, we have Fig. 6A, which ranks them according to the number of publications between 2012 and 2023. In this way, it was observed that the author with the highest number of published works was Cloete S from Norway, with 6 articles published, accounting for 6.89% of the total articles in the field. We have Del Pozo from Spain, with 3 published articles. The remaining authors considered here had 2 publications each, but they are ranked in order of relevance. The last author had only one publication. Fig. 6B graphically shows the co-citation relationship between the authors. Thus, the constructed visualization map presented considerable Q value and silhouette values (Q = 0.597; silhouette = 0.8463), indicating a certain homogeneity between the publications and the themes addressed. In addition, 8 clusters were identified: “SMR with CCUS” (#0), “CO2 reduction” (#1), “techno-economic” (#2), “greenhouse gases” (#3),“sorption enhanced reforming” (#4), “methane catalytic” (#5), “methane pyrolysis” (#6) and “CO2 sequestration” (#7).
Rank | Journal title | Country | Count | Percentage (%) | IF (2021) | Quartile in category (2021) | H-index |
---|---|---|---|---|---|---|---|
1 | International Journal of Hydrogen Energy | England | 13 | 14.94 | 7.139 | Q2 | 7 |
2 | Energies | Switzerland | 9 | 10.34 | 3.252 | Q3 | 3 |
3 | Energy Conversion and Management | England | 9 | 10.34 | 11.533 | Q1 | 5 |
4 | Journal of Cleaner Production | USA | 6 | 6.90 | 11.072 | Q1 | 3 |
5 | Energy | England | 4 | 4.60 | 8.857 | Q1 | 3 |
6 | Renewable Sustainable Energy Reviews | USA | 4 | 4.60 | 16.799 | Q1 | 3 |
7 | ACS Sustainable Chemistry Engineering | USA | 2 | 2.30 | 9.224 | Q1 | 1 |
8 | Applied Energy | England | 2 | 2.30 | 11.446 | Q1 | 2 |
9 | Applied Sciences Basel | Switzerland | 2 | 2.30 | 2.838 | Q2 | 2 |
10 | Energy Policy | England | 2 | 2.30 | 7.576 | Q1 | 1 |
• RQ3 What are the main emerging subfields of research on blue hydrogen production in recent literature?
Table 4 lists the ranking of the top 10 most cited papers and their basic information, such as the journal of publication, author, and year of publication. It was revealed that all ranked articles were published in 2020, with the majority being from 2021. The most impactful paper in terms of citation count was written by Howarth et al. (2021),15 with 165 citations, followed by the article written by Yu et al. (2021),12 with 113 citations. In third place was the paper produced by Fan et al. (2021),70 which received 79 citations. Regarding the number of authors per published article, it was observed that all articles in the top 10 had co-authors, with an average of 4.9 authors per article.
Rank | Title | Journal | First Author | Year | Citations |
---|---|---|---|---|---|
1 | How green is blue hydrogen? | Energy Science & Engineering | Howarth, Robert W. | 2021 | 165 |
2 | Insights into low-carbon hydrogen production methods: green, blue and aqua hydrogen | International Journal of Hydrogen Energy | Yu, Minli | 2021 | 113 |
3 | Low-carbon production of iron and steel: technology options, economic assessment, and policy | Joule | Fan, Zhiyuan | 2021 | 79 |
4 | A framework for assessing economics of blue hydrogen production from steam methane reforming using carbon capture storage & utilisation | International Journal of Hydrogen Energy | Khan, Muhammad H. A. | 2021 | 55 |
5 | The role of carbon capture and storage in the energy transition | Energy & Fuels | Lau, Hon Chung | 2021 | 54 |
6 | On the climate impacts of blue hydrogen production | Sustainable Energy & Fuels | Bauer, Christian | 2021 | 51 |
7 | Process simulations of blue hydrogen production by upgraded sorption enhanced steam methane reforming (SE-SMR) processes | Energy Conversion and Management | Yan, Yongliang | 2020 | 49 |
8 | Hydrogen and hydrogen-derived fuels through methane decomposition of natural gas – GHG emissions and costs | Energy Conversion and Management: X | Timmerberg, Sebastian | 2020 | 49 |
9 | Comparative assessment of blue hydrogen from steam methane reforming, autothermal reforming, and natural gas decomposition technologies for natural gas-producing regions | Energy Conversion and Management | Oni, A. O. | 2022 | 43 |
10 | The economics and the environmental benignity of different colors of hydrogen | International Journal of Hydrogen Energy | Ajanovic, A. | 2022 | 42 |
A co-citation network was built through CiteSpace on a visualization map to establish the co-citation relationship, as shown in Fig. 8A. The citation network obtained comprises 160 nodes, and to facilitate the analysis of the data presented by it, we can group them into 11 main subclusters. Through the software, it is possible to access the Q value of modularity, a quality measure of the grouping of nodes in communities or modules in a network, which can vary between −1 and 1 in the presented structure (Fig. 8A). The Q modularity value was 0.5913, suggesting that the nodes are substantially connected within their communities. Furthermore, it is also possible to see that the weighted average silhouette value between subclusters #0 and #10 was 0.7967, indicating the quality of the relationship between the clusters. In order to present a view of the relationships of the co-citation network of references in a temporal way, Fig. 8B reveals the characteristics of the hot spots for current and future research in this field. The most relevant cluster for this study was “assessing economy” (#0), the second largest was “low-emission hydrogen” (#1), and the third was “steam methane” (#2). Suggesting that there was an earlier development about the other clusters, cluster 4 (hydrogen) initially focuses on hydrogen production. It can also be considered that cluster 2 (low-emission hydrogen) is currently a research hot spot. Thus, it can be observed that there is an increase in the contextual bias of publications based on the theme of hydrogen production with low pollutant emissions.
• RQ4 What are the main hotspots used in the literature search?
Keyword co-occurrence analysis plays a critical role in bibliometric analysis. By conducting this procedure, it is possible to visualize knowledge networks, observe relationships between concepts, and identify emerging trends in scientific literature. Thus, Fig. 9 was created to present a map containing the density of keyword frequency based on the selected database. The analysis revealed that 327 keywords were identified across the 87 obtained articles. Furthermore, keywords with the highest number of occurrences are represented as hotspots. Table 5 provides a list of the top 20 keywords based on their frequency of occurrence. Notably, “blue hydrogen” and “hydrogen production” were the most frequent, with 18 and 12 occurrences, respectively. However, the remaining keywords primarily refer to the main processes involved in blue hydrogen production and other types of hydrogen, such as CO2 capture and methane reforming.
Fig. 9 Density map of keywords generated by the VOSviewer showing the hotspot on blue hydrogen research. |
Rank | Keyword | Occurrences | TLS | Rank | Keyword | Occurrences | TLS |
---|---|---|---|---|---|---|---|
a TLS: total link strength. | |||||||
1 | Blue hydrogen | 18 | 43 | 11 | Hydrogen economy | 7 | 18 |
2 | Hydrogen production | 12 | 42 | 12 | Steam methane reforming | 7 | 18 |
3 | Life cycle assessment | 10 | 41 | 13 | Techno-economic analysis | 6 | 21 |
4 | CO2 capture | 10 | 26 | 14 | Methane pyrolysis | 6 | 14 |
5 | Green hydrogen | 10 | 23 | 15 | Carbon-dioxide capture | 5 | 18 |
6 | Natural gas | 9 | 32 | 16 | Power-to-gas | 5 | 17 |
7 | Hydrogen | 8 | 27 | 17 | Storage | 5 | 17 |
8 | Methane | 8 | 25 | 18 | Decarbonization | 5 | 13 |
9 | Electrolysis | 7 | 22 | 19 | H-2 production | 5 | 13 |
The visualization map obtained through VOSviewer indicated 6 clusters, where all the keywords identified in the data collection could be divided into the following categories: “blue hydrogen study”, “hydrogen production study”, “green hydrogen production study”, “CO2 capture and storage study”, “techno-economic study” and “technological study” as shown in Fig. 10A. The purpose of presenting the current scenario in blue hydrogen research is to analyze the prominent topics up to the present moment. In the “blue hydrogen study” cluster, the main keywords assigned are “coal”, “challenges”, and “gas”. As for the “hydrogen production study” cluster, the most relevant keywords are “hydrogen economy”, “methane pyrolysis”, and “carbon dioxide capture”. In the “green hydrogen production study” cluster, the most frequent keywords are “renewable energy”, “cost”, and “ammonia”. The “CO2 capture and storage study” cluster commonly includes terms such as “chemical looping”, “optimization” and “design”. The “techno-economic study” cluster mainly features “liquid hydrogen” and “economic analysis”. The sixth cluster, “technologies”, has keywords with higher frequencies, such as “process intensification” and “partial oxidation”.
Fig. 10B was created based on the Average Article Year (AAY), displaying the frequency at which the gathered keywords were cited in articles from 2020 to 2023. By using different colours in the overlay visualization map, occurrences of these terms can be delimited. It can be observed that the publications in 2020 were focused on hydrogen production and carbon capture but in a limited number. However, starting in 2022, there was a significant increase in work in this area, as evidenced by the growth in the co-occurrence of keywords such as “hydrogen economy” (AAY = 2022.71), “liquid hydrogen” (AAY = 2022.67), “hydrogen storage” (AAY = 2022.67), and “renewable energy” (AAY = 2022.67), visualized by using VOSviewer overlay visualization. Thus, it is implied that these keywords are likely to be among the hotspots in blue hydrogen research in the coming years.
Initially, our research focused on the period from 2012 to 2023. However, it was observed that publications related explicitly to blue hydrogen only emerged starting in 2020. The bibliometric data analysis revealed that until May 2023, only 87 articles were published, considering they met the research criteria outlined in Fig. 1. The Web of Science platform found 1138 citations, with 629 occurring in 2022. Although research in this field is still in its early stages, 37 countries have contributed to developing blue hydrogen research. Among these contributing countries, the United States showed the highest productivity in this research field, with 16 published articles, closely followed by England, with 13 publications. However, even though the United States leads the ranking in terms of scientific productivity, its first studies in this area were only published in 2021, indicating the current growth trajectory of this field. It can be considered that the rise of these studies is directly driven by the country's increasing interest in clean fuels, particularly in the transportation sector and hydrogen production for fuel cells.71 Therefore, it is expected that the number of contributions will continue to grow in the academic landscape, given the significant number of countries that have dedicated themselves to scientific production in this field over the past two years.
In order to classify the main contribution vectors in the academic research sector, the total number of citations and the H-index of significant countries were considered. Thus, it was found that the United States takes a prominent position in the world both in quantitative terms of citations as in the H-index, closely followed by England, which has a similar H-index, considering that this parameter is essential to indicate the most expressive collaborators in a given field of study and the impact of their publications. In addition, it is worth mentioning that Canada and China also played a prominent role in the central regions where these studies were concentrated. Furthermore, when considering the top 10 institutions involved in the scientific production of research for the hydrogen category addressed, the United Kingdom leads with 4 institutions, thus adding the highest number of collaborations among the analyzed ranking. Therefore, the progress of academic interest and the growth of the approach to this topic in the United Kingdom is notorious, a fact evidenced by the significant participation of these institutions in the production of these studies. However, even if this is considerable progress for studying the blue hydrogen category in this region, it is essential to note that England had a substantially lower number of citations than the United States. In addition, Scotland has a lower number than England both in citations and when compared to its respective H-index, revealing that in addition to the significant participation among the most relevant institutions, it is still necessary to guarantee the quality of these works in the scientific scope of search. With this, it should be highlighted that the financial subsidy for research associated with the participation and encouragement of human resources is essential for the growth of production and quality of works related to the category of hydrogen analyzed in this study. Thus, knowing the relevant role that financial incentives play in supporting the development of new scientific productions, among the top 10 funding agencies, South Korea comprises 8.046% of participation in economic incentives for research groups and institutions. This proves consistent because South Korea has acted as a world reference with an economy based on hydrogen.72
Regarding the prominent journals in the field covered, the three most productive, within the top 10, are the International Journal of Hydrogen Energy (IF = 7.139, Q2), Energies (IF = 3.252, Q3), and Energy Conversion and Management (IF = 11533, Q1). However, even considering that the scientific journal Energy Conversion and Management is in third place in the total number of publications, its IF value and classification as Q1 indicate its relevance for the academic scope based on the number of citations this journal received. However, it is noteworthy that even though the ranking presented having the number of publications of each of the newspapers as a starting point, the newspaper Renewable Sustainable Energy Reviews is more prominent in terms of impact factor, thus showing the quality of its publications and their relevance for the scientific community involved with this research topic, since it is essential for researchers that scientific journals have high visibility and reach so that more significant numbers of submissions of papers for publication are encouraged. A dual-map overlay was employed to analyze the flow of information between journals, revealing scientific portfolio trends comprehensively. This approach proved to be a valuable resource for understanding knowledge dynamics. The results indicated that the published studies focused mainly on journals in the following areas: physics, materials, and chemistry. In addition, all analyzed journals cited other journals in the same areas.
This study's co-authorship analysis was crucial in defining the cooperation connections between different authors, institutions, and countries. This assessment is based on understanding the relationship between the items through the number of co-authored documents. To obtain how this cooperation occurred in terms of proximity between the works, the TLS indicator played an essential role in supporting the discussions. The higher the TLS value, the more frequent the cooperation between authors, institutions, and countries. Therefore, based on recent data, it was possible to assess that the United States established considerable collaborations with England and Canada as notable research centres. Such information infers a perceptible sharing of collaboration between these countries regarding academic productivity, which is directed toward developing hydrogen production. This exchange of information between researchers is an essential factor for the advancement and visibility of research in any sector. Thus, according to the results analyzed, it is consistent to state that there is cooperation among the academic agents involved in this field, suggesting that such collaborations reaffirm the relevance of these countries as currently more productive in the topic of blue hydrogen, where they can play essential roles in the field. Creating new innovations and solutions specifically tailored for this industry segment, working together to ensure the ongoing positive impacts they bring to their respective productions. When performing the co-authorship analysis between institutions, the network map produced revealed, for example, close collaborations with the University of Calgary, Canada, with the Swiss Federal Institutes of Technology Domain, Switzerland, Universidad Politécnica de Madrid, Spain, and SINTEF, from Norway. These data prove the active participation of these institutions in developing new research projects through mutual collaboration, driving advancements, and paving the way for significant contributions. With an author co-authorship analysis, it was possible to verify that Cloete S, from Norway, had the highest number of publications related to blue hydrogen. It is possible to assess the prominence of his participation in this field based on these discoveries, as they show how this author cooperated with the academic community with many works, enriching the literature with his approaches. Del Pozo CA, Alvaro AJ, and Anthony EJ were other authors with relevant published works. Based on the retrieved information (WoS), it was found that the authors who stood out in the number of publications are affiliated with institutions that also hold a prominent position in the area, institutions that have already been presented in this study. Thus, the integration of human resources and opportunities provided by specialized research institutions boost the progress and visibility of their contributions to the scientific community. The results analyzed in this study reinforce the importance of these authors and the institutions in which they are affiliated, pointing to the significant impact they can have on the research sector, cooperating for the growth and development of new techniques and improvement of production routes to blue hydrogen.
The results of the co-citation analysis were obtained based on the measurement of the relationship between documents. In the case of co-citation analysis between authors, the prominence of each author is determined by the number of times their articles are cited by the same work. This approach is commonly used in order to assess the relevance of an author, as well as their impact and influence in the academic field. Thus, our results show that Howarth R. W. stands out as the most cited author, and it can be stated that his works significantly impact the research sector. Howarth R. W. has an H-index of 76, which shows this researcher's degree of productivity and influence. In addition, his last work in blue hydrogen was published in 2022. Fig. 6B divides the authors into eight clusters, where these represent the main research areas, such as “SMR with CCUS” (#0), “CO2 reduction” (#1), “techno-economic” (#2), and “greenhouse gases” (#3). When considering these fields, it is possible to observe where the focus of researchers has been concentrated in recent years, given the dynamic character of the research sector, which seeks to promote discussions aimed at solving challenges and developing new approaches. Thus, given the analysis of the visualization map, the hydrogen production routes and concerns arising from the emission of pollutants into the atmosphere have recently received notable attention among researchers. Thus, studies aimed at assessing the efficiency and profitability of these means of production have provided an environment for discussion that seeks to ensure the sustainable implementation of blue hydrogen as an energy vector, optimizing the processes already used and ensuring future improvements. However, the authors noted additional challenges. These include, for the most part, the need for adequate infrastructure to capture and store carbon dioxide from production processes. It is also worth highlighting the obstacles involved in making projects for the safe transportation and distribution of the hydrogen that has been produced feasibly. Therefore, the increase in studies in this area corroborates the improvement of these processes, making blue hydrogen increasingly commercially attractive.
The most cited studies in blue hydrogen occurred between 2020 and 2022, as evidenced by the top 10 presented in Table 4, revealing the still-recent nature of this field of research. The fact that Howarth R. W. wrote the most cited work indicates the significant effect and relevance of this research in particular because, when considering the number of productions obtained from the database, this author stood out among the others as evidenced by the impact of his work on the academic community. When observing the still recent period of the beginning of the publications, it is essential to highlight that the production of blue hydrogen is a relatively new approach compared to other hydrogen production routes. Therefore, scientific knowledge constantly expands as more researchers explore its potential. Fig. 8B offers a chronological representation of the co-citation clusters of references, providing exciting insights into dynamic changes and development trends over different periods. Notably, the largest cluster identified is that of “assessing economy” (#0) (Howarth et al., 2021; Bauer et al., 2022),15,22 closely followed by the cluster of “low-emission hydrogen” (#1) (Noussan et al., 2020; Antzaras et al., 2022)11,14 and “steam methane” (#2) (Longden et al., 2022).73 It can be said that clusters 4 (hydrogen) and 9 (economy fairway) occurred earlier than the others. However, they remained relevant over time, being themes addressed until recently.
On the other hand, clusters 0 (assessing economy) and 1 (low-emission hydrogen) are currently highlighted in the area, revealing their possible participation in future research. Thus, from the data observed in each map, it is possible to assess how the trends for this field are moving towards applying blue hydrogen in a sustainable economy, considering the evolution of publications in the context of the growing demand for clean energy sources. The initial groupings indicate the established baseline for further studies, while the current groupings reflect this sector's most recent challenges and opportunities. This diversity of areas of interest demonstrates the dynamism of research in this hydrogen category since, by analyzing the co-citation of references, one can understand how the different themes are connected and their distribution over time. This provides the foundation for future research, collaborations, and advancements in blue hydrogen production.
In the field of bibliometrics, the analysis of frequently mentioned keywords plays an essential role in identifying highlighted categories, in addition to helping to monitor the development of a particular research theme. By using the VOSviewer to perform a keyword co-occurrence analysis, it was possible to identify 6 distinct clusters based on the keywords present in the WoSCC database: “blue hydrogen study”, “hydrogen production study”, “green hydrogen production study”, “CO2 capture and storage study”, “techno-economic study” and “technological study”. These clusters indicate the areas of most significant interest and investigation within the field of hydrogen, ranging from the study of blue hydrogen to the evaluation of different technologies and economic aspects related to the production and use of hydrogen. In addition, the CO2 capture and storage study reflects the concern with sustainability and the environmental impact of producing this fuel. These results suggest that this field of research is constantly expanding, addressing aspects ranging from efficiency and economic viability to reducing carbon emissions.
Regarding the analysis of the co-occurrence of keywords carried out in this study, it was possible to obtain an overview of the main topics addressed, identify future directions for these studies, and provide an evaluation consistent with the current scenario. This information is crucial for directing research efforts and promoting significant advancements in the large-scale application of blue hydrogen. By identifying the research clusters, such as the “blue hydrogen study” and “green hydrogen production study”, it is possible to perceive that the search for a sustainable energy matrix has had undeniable growth, even though both areas of study deal with technologies that are still new in the hydrogen tracking. The fact that there is a significant number of studies, considering a short period since the beginning of publications, indicates an increase in interest and awareness of new approaches to hydrogen production by processes that emit less and fewer pollutants. This can be attributed to global concerns about climate change and the need to find sustainably competent solutions.
It is important to emphasize that the presence of the “techno-economic study” cluster suggests a focus on assessing the viability of blue hydrogen to contribute to the potential that this fuel can offer to the economy, an aspect essential for its adoption on a large scale. Effectively integrating this technology into current energy systems in a commercially viable manner. However, although the production of blue hydrogen is in its initial stages, the data shows that the development takes place to meet the energy demand. However, even if the number of works published in this field has not yet reached expressive levels, the focus observed from the analysis of production routes to the evaluation of the viability of new projects reflects the need to understand and improve the different aspects of this technology by some of the researchers to incorporate blue hydrogen in a decisive way in the economy and the energy sector.
The data obtained indicate that the keywords “hydrogen economy”, “liquid hydrogen”, “hydrogen storage,” and “renewable energy” are the main hotspots for future research, which highlights the concerns and current themes addressed among the academics concerning energy production having blue hydrogen as a vector.
(i) Hydrogen economy. The presence of this keyword indicates the growing approach to this theme since there is a significant interest in building a conscious economy in the quest to reduce the emission of pollutants, as well as the need to implement a source of energy in the global energy system of power that meets social and market demands. However, for the production of blue hydrogen, it is necessary to have government incentives and the development of specialized infrastructure focused on the safety and maintenance of this fuel within the energy matrix. Thus, given the data obtained, it is clear that the insertion of hydrogen as an energy vector is a growing agenda in the academic sector, which continuously helps in the development of technologies and provides the emergence of new prospects for the global energy market, improving the techniques already implemented in the hydrogen production chain and cooperating for significant and dynamic growth of this segment.
(ii) Liquid hydrogen and hydrogen storage. The fact that these terms appear together within the research environment reinforces the relevance of the theme of safe hydrogen storage concerning the other topics considered. Hydrogen, in its liquid form, has high energy efficiency. However, there are several challenges regarding its storage and transport.70,74,75 Liquid hydrogen requires low temperatures and adiabatic conditions for transport through pipelines. However, the costs arising from the initial processes of implementing an infrastructure that serves this distribution are still the limiting factor for the widespread use of this system. In addition, an advanced refrigeration system is also necessary to guarantee the required conditions for storage. Tanks or containers with certain pressure conditions can be used. However, this method is indicated for short distances. Whether in its liquid or gaseous form, hydrogen storage is an element that must be considered in any project implementation study in this field, as ensuring the safety and efficiency of the production chain is essential for introducing hydrogen into the energy system. Thus, the need to develop research aimed at understanding such factors is necessary for the viable and economical application of this fuel, considering that there is a need for means to store hydrogen in large volumes to supply the growing demand.
(iii) Renewable energy. Faced with the emergence of new prospects for reducing energy production by conventional routes, which are based on the use of fossil fuels, the growth in the number of studies, as well as the development of new technologies for energy production by sustainable means, are indicative of the transition of the global energy system to new heights. Integrating clean energy sources already widely used, such as solar and wind, with other forms of energy, such as hydrogen, is fundamental for achieving social and economic advancements. The presence of “renewable energy” as one of the potential hotspots for the scientific field shows the connection between emerging topics in the field of blue hydrogen. In this way, it is clear that in the current scenario of the research sector, the productions directed to this type of hydrogen have grown substantially. However, the number of projects for implementing this energy vector globally is still in its initial stages. Therefore, the continuous production of research in these areas helps to improve existing technologies and explore new horizons for application in the energy market, seeking new solutions for the current challenges.
However, some limitations were identified and are relevant to mention. The first was that the database obtained by WoS contained a small number of articles to be analyzed, making it difficult to build more accurate visualization maps in the software used for observing data more complexly and understanding the interconnections between works. Another limitation found is that the data obtained in this study may differ from the current WoS information due to the constant updates that the platform performs as new works are published.
Monitoring the progress of the global energy transition is necessary for synchronicity and economic returns to occur, as among the financial risks facing the development of the hydrogen economy is the making of considerable investments in infrastructure and uncertain market acceptance. In this sense, studies are developed that aim at application and economic forecasts. Lee et al. (2023) carried out a technical and financial analysis of the production of blue hydrogen against grey hydrogen. They listed the operational costs in six cases, confirming the high cost for development, application and maintenance.77
In summary, although the initial cost of blue hydrogen is higher than some alternatives, its potential for cost savings and lower environmental impact make it an attractive option. Implementing enabling policies and continued development of technologies can boost their economic viability and significantly contribute to the global transition to a low-carbon economy. These values are indicative and may vary depending on the region, specific production methods and market conditions.
There has been significant growth in the volume of patents granted or deposited in recent years, with industries and universities playing a vital role in this increase. Industries account for more than 46% of patents deposited or granted, while academic institutions hold about 54%. This increase can be attributed to the development of engineering and computational tools that allow for deeper analyses and applications of routes related to the production of blue hydrogen. Fig. 11 presents a graph that shows this growth in the volume of patents over the last few years.
It is also important to highlight that some countries stand out regarding the number of patents deposited. China, the United States, and South Korea occupy the 1st, 2nd, and 3rd places in the ranking, respectively. The Chinese are responsible for about 54% of the patents granted, while the North Americans and the South Koreans hold 19% each. It is worth mentioning that the predominant language in the scientific writing of these patents is English. In summary, the patent scenario for the production of blue hydrogen is promising. It has been gaining prominence in research, seeking various applications for these production routes and this product, which is vital for global energy development.
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