Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices

Ming-Yue Bi; Qin-Long Hong; Meng Liu; Fei Wang; Hai-Xia Zhang; Jian Zhang

doi:10.1039/D1CC01249E

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Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices†

Ming-Yue Bi,^a Qin-Long Hong,^a Meng Liu,^b Fei Wang,

^a Hai-Xia Zhang

*^a and Jian Zhang

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhanghaixia@fjirsm.ac.cn, zhj@fjirsm.ac.cn

^b Key Lab for Sport Shoes Upper Materials of Fujian Province, Fujian Huafeng New Material Co., Ltd, Putian, China

Abstract

Two cage-based boron imidazolate helices were prepared in achiral reaction systems by mixing a C₃ symmetric rigid ligand, KBH(bim)₃, and a long flexible dicarboxylic acid ligand. The presence of an appropriate chiral inducer can control the helical orientation of bulk samples, which further acts on the enantioselective separation of racemic 1-phenylethanol.

This article is part of the themed collections: 10th Anniversary of the Youth Innovation Promotion Association of the Chinese Academy of Science and 2021 Emerging Investigators

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DOI: https://doi.org/10.1039/D1CC01249E
Article type: Communication
Submitted: 08 Mar 2021
Accepted: 14 Apr 2021
First published: 15 Apr 2021

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Chem. Commun., 2021,57, 5020-5023

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Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices

M. Bi, Q. Hong, M. Liu, F. Wang, H. Zhang and J. Zhang, Chem. Commun., 2021, 57, 5020 DOI: 10.1039/D1CC01249E

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Chemical Communications

Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices†

Abstract

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Chiral induction in boron imidazolate frameworks: the construction of cage-based absolute helices

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