Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

Ashish Singh; Syamantak Roy; Chayanika Das; Debabrata Samanta; Tapas Kumar Maji

doi:10.1039/C8CC01291A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis†

Ashish Singh,

^a Syamantak Roy,

^a Chayanika Das,

^a Debabrata Samanta

^a and Tapas Kumar Maji

*^a

Author affiliations

* Corresponding authors

^a Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560064, India
E-mail: tmaji@jncasr.ac.in
Tel: +91-8022082826

Abstract

We report the design and synthesis of two Co²⁺ and Zn²⁺ phthalocyanine (PC)-based redox active metal–organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co²⁺ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.

This article is part of the themed collection: 20th Anniversary of the CRSI: Celebrating Indian Chemistry in ChemComm

Download options Please wait...

Supplementary files

Supplementary information PDF (939K)

Article information

DOI: https://doi.org/10.1039/C8CC01291A
Article type: Communication
Submitted: 13 feb 2018
Accepted: 27 mar 2018
First published: 29 mar 2018

Download Citation

Chem. Commun., 2018,54, 4465-4468

Permissions

Request permissions

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

A. Singh, S. Roy, C. Das, D. Samanta and T. K. Maji, Chem. Commun., 2018, 54, 4465 DOI: 10.1039/C8CC01291A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

Social activity

Search articles by author

Spotlight

Advertisements