Issue 31, 2017

Coordinated nitrate anions can be directional π-hole donors in the solid state: a CSD study

Abstract

A comprehensive Cambridge Structure Database evaluation reveals grouping and significant van der Waals overlap of sp2 O-atoms above/below the N-atom of coordinated nitrate anions. Overlap of van der Waals shells increases with increased coordination and 84% of close contacts involve anti-electrostatic NO3⋯NO3 interactions.

Graphical abstract: Coordinated nitrate anions can be directional π-hole donors in the solid state: a CSD study

Supplementary files

Article information

Article type
Communication
Submitted
11 jún 2017
Accepted
14 júl 2017
First published
17 júl 2017

CrystEngComm, 2017,19, 4485-4488

Coordinated nitrate anions can be directional π-hole donors in the solid state: a CSD study

T. J. Mooibroek, CrystEngComm, 2017, 19, 4485 DOI: 10.1039/C7CE01266G

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