Issue 39, 2016

An efficient perovskite solar cell with symmetrical Zn(ii) phthalocyanine infiltrated buffering porous Al2O3 as the hybrid interfacial hole-transporting layer

Abstract

A new Zn(II) phthalocyanine (Pc) based low bandgap HTM is introduced for perovskite solar cells. Steady state and time-resolved photoluminescence (PL) measurements indicated an evenly matched hole extraction efficiency between sym-HTPcH and spiro-OMeTAD. On account of the low film quality and resulting high recombination, Zn(II) Pc normally cannot work as an effective HTM. We adopted insulating Al2O3 for the infiltration of sym-HTPcH to form a hybrid interfacial buffer layer, affording perovskite solar cells (PSCs) with an average PCE value of up to 12.3%, which is a significant improvement with respect to the control cell without the meso-Al2O3 layer (4.21%) and is the highest value ever reported for Zn(II) phthalocyanine based devices under AM1.5G standard conditions. A hysteresis test revealed that our device structure with the new HTM exhibited a balanced charge extraction behaviour.

Graphical abstract: An efficient perovskite solar cell with symmetrical Zn(ii) phthalocyanine infiltrated buffering porous Al2O3 as the hybrid interfacial hole-transporting layer

Supplementary files

Article information

Article type
Paper
Submitted
18 máj 2016
Accepted
04 júl 2016
First published
05 júl 2016

Phys. Chem. Chem. Phys., 2016,18, 27083-27089

An efficient perovskite solar cell with symmetrical Zn(II) phthalocyanine infiltrated buffering porous Al2O3 as the hybrid interfacial hole-transporting layer

P. Gao, K. T. Cho, A. Abate, G. Grancini, P. Y. Reddy, M. Srivasu, M. Adachi, A. Suzuki, K. Tsuchimoto, M. Grätzel and M. K. Nazeeruddin, Phys. Chem. Chem. Phys., 2016, 18, 27083 DOI: 10.1039/C6CP03396B

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