Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded meso–meso-linked homo- and heterodimers, and meso-β-linked dimers. The photophysical and electrochemical properties of the dimers are reported.
R. Xiong, A. I. Arkhypchuk, D. Kovacs, A. Orthaber and K. Eszter Borbas, Chem. Commun., 2016, 52, 9056 DOI: 10.1039/C6CC00516K
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