Issue 45, 2015

Accessing perfluoroalkyl nickel(ii), (iii), and (iv) complexes bearing a readily attached [C4F8] ligand

Abstract

The [C4F8] ligand was shown to support well-defined terpyridyl nickel complexes in the +2 and +3 oxidation states. Notably, a cyclic voltammetry study of the nickel(III) species indicates that an additional oxidation is accessible, providing a family of related fluoroalkyl nickel complexes spanning the +2 to +4 oxidation states.

Graphical abstract: Accessing perfluoroalkyl nickel(ii), (iii), and (iv) complexes bearing a readily attached [C4F8] ligand

  • This article is part of the themed collection: Fluorine

Supplementary files

Article information

Article type
Communication
Submitted
11 máj 2015
Accepted
05 jún 2015
First published
05 jún 2015

Dalton Trans., 2015,44, 19443-19446

Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand

S. Yu, Y. Dudkina, H. Wang, K. V. Kholin, M. K. Kadirov, Y. H. Budnikova and D. A. Vicic, Dalton Trans., 2015, 44, 19443 DOI: 10.1039/C5DT01771H

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