Issue 52, 2012
From the journal:

Chemical Communications

Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function†‡

Kenji Hirai,a   Shuhei Furukawa,*bc   Mio Kondo,bc   Mikhail Meilikhov,bc   Yoko Sakata,bc   Osami Sakatad  and  Susumu Kitagawa*abc  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

b Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan
E-mail: shuhei.furukawa@icems.kyoto-u.ac.jp
Fax: +81-75-753-9869
Tel: +81-75-753-9820

c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park bldg #3, Shimogyo-ku, Kyoto, Japan

d Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5198, Japan

Abstract

Spatiospecific functionalisation of a shell crystal was performed in a core–shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

Graphical abstract: Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

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Article information

DOI
https://doi.org/10.1039/C2CC31421E
Article type
Communication
Submitted
26 feb 2012
Accepted
30 mar 2012
First published
02 apr 2012

Chem. Commun., 2012,48, 6472-6474

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Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

K. Hirai, S. Furukawa, M. Kondo, M. Meilikhov, Y. Sakata, O. Sakata and S. Kitagawa, Chem. Commun., 2012, 48, 6472 DOI: 10.1039/C2CC31421E

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