Issue 9, 2012
From the journal:

Chemical Communications

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach†‡

S. M. Ibrahim Al-Rafia,a   Adam C. Malcolm,a   Robert McDonald,a   Michael J. Fergusona  and  Eric Rivard*a  

* Corresponding authors

a Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada
E-mail: erivard@ualberta.ca
Tel: +1 780-492-4255

Abstract

A stable Si(II) dihydride complex, IPr·SiH2·BH3 (IPr = [(HCNDipp)2C:]; Dipp = 2,6-iPr2C6H3), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported.

Graphical abstract: Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC17101E
Article type
Communication
Submitted
16 nov 2011
Accepted
07 dec 2011
First published
12 dec 2011

Chem. Commun., 2012,48, 1308-1310

Permissions

Request permissions

Efficient generation of stable adducts of Si(II) dihydride using a donor–acceptor approach

S. M. I. Al-Rafia, A. C. Malcolm, R. McDonald, M. J. Ferguson and E. Rivard, Chem. Commun., 2012, 48, 1308 DOI: 10.1039/C2CC17101E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements