A highly divergent synthesis of α-fuco-, α-6-deoxy-allo-, α-6-deoxy-altro-pyranosides has been achieved. This route utilizes a Wharton rearrangement as part of a new post-glycosylation transformation strategy.
H. L. Wang and G. A. O'Doherty, Chem. Commun., 2011, 47, 10251 DOI: 10.1039/C1CC13837E
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