Issue 25, 2009
From the journal:

Journal of Materials Chemistry

Enhanced H2adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O†‡

Zeric Hulvey,a   Eduardo H. L. Falcao,a   Juergen Eckerta  and  Anthony K. Cheetham*b  

* Corresponding authors

a Materials Research Laboratory, University of California, Santa Barbara, CA, USA
E-mail: zhulvey@chem.ucsb.edu

b Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, UK
E-mail: akc30@cam.ac.uk

Abstract

A porous coordination polymer containing zinc, 1,2,4-triazolate, and tetrafluoroterephthalate displays a high physisorptive hydrogen adsorption enthalpy of 8 kJ/mol, as a result of fluorine atoms exposed to the pore surface and the structure's small pore size.

Graphical abstract: Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

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Article information

DOI
https://doi.org/10.1039/B900879A
Article type
Communication
Submitted
15 jan 2009
Accepted
09 mar 2009
First published
19 mar 2009

J. Mater. Chem., 2009,19, 4307-4309

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Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

Z. Hulvey, E. H. L. Falcao, J. Eckert and A. K. Cheetham, J. Mater. Chem., 2009, 19, 4307 DOI: 10.1039/B900879A

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