Catalytic conversion of butadiene to ethylbenzene overthe nanoporous nickel(II) phosphate, VSB-1

Jong-San Chang; Sang-Eon Park; Qiuming Gao; Gérard Férey; Anthony K. Cheetham

doi:10.1039/B009160J

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Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(ii) phosphate, VSB-1

Jong-San Chang,^a Sang-Eon Park,*^b Qiuming Gao,^a Gérard Férey^c and Anthony K. Cheetham*^a

Author affiliations

* Corresponding authors

^a Materials Research Laboratory, University of California, Santa Barbara, CA, USA.
E-mail: cheetham@mrl.ucsb.edu

^b Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), P.O. Box 107, Yusung, Taejon, Korea.
E-mail: separk@pado.krict.re.kr

^c Institut Lavoisier, Université de Versailles Saint Quentin, UMR CNRS 173, 45 avenue des Etats-Unis, Versailles Cedex, France.

Abstract

The large-pore nickel(II) phosphate, VSB-1, shows excellent selectivity (>80%) for the dehydrocyclodimerization of butadiene to ethylbenzene at 400 °C; conversion to 4-vinylcyclohexene and oligomeric byproducts is <5% in each case.

This article is part of the themed collection: In celebration of Tony Cheetham’s 70th birthday

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Article information

DOI: https://doi.org/10.1039/B009160J
Article type: Communication
Submitted: 14 nov 2000
Accepted: 09 mar 2001
First published: 18 apr 2001

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Chem. Commun., 2001, 859-860

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Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate, VSB-1

J. Chang, S. Park, Q. Gao, G. Férey and A. K. Cheetham, Chem. Commun., 2001, 859 DOI: 10.1039/B009160J

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