Electrophilic functionalization of a cyclometallated ruthenium complex, an easy entry to new organometallic synthons

(Note: The full text of this document is currently only available in the PDF Version )

Christophe Coudret and Sandrine Fraysse


Abstract

With the regiospecific halogenation of the complex [Ru- (bpy)2L1]+ (bpy = 2,2′-bipyridine, HL1 = 2-phenylpyridine) new organometallic starting materials are now available.


References

  1. A.-C. Ribou, J.-P. Launay, K. Takahashi, T. Nihira, S. Tarutani and C. W. Spangler, Inorg. Chem., 1994, 33, 1325 CrossRef CAS; C. Patoux, C. Coudret, J.-P. Launay, C. Joachim and A. Gourdon, Inorg. Chem., 1997, 36, 5037 CrossRef CAS.
  2. M. Beley, S. Chodorowski-Kimmes, J.-P. Collin, P. Laine, J.-P. Launay and J.-P. Sauvage, Angew. Chem., Int. Ed. Engl., 1994, 33, 1775 CrossRef.
  3. S. Chodorowski-Kimmes, M. Beley, J.-P. Collin and J.-P. Sauvage, Tetrahedron Lett., 1996, 37, 2963 CrossRef.
  4. E. C. Constable and J. M. Holmes, J. Organomet. Chem., 1986, 301, 203 CrossRef CAS.
  5. M. Beley, J.-P. Collins and J.-P. Sauvage, Inorg. Chem., 1993, 32, 4539 CrossRef CAS.
  6. M. Beley, J.-P. Collin, R. Louis, M. Metz and J.-P. Sauvage, J. Am. Chem. Soc., 1991, 113, 8521 CrossRef CAS.
  7. J.-P. Sutter, D. Grove, M. Beley, J.-P. Collin, N. Veldman, A. Spek, J.-P. Sauvage and G. van Koten, Angew. Chem., Int. Ed. Engl., 1994, 33, 1282 CrossRef.
  8. C. Patoux, J.-P. Launay, M. Beley, S. Chodorowski-Kimmes, J.-P. Collin, S. James and J.-P. Sauvage, J. Am. Chem., Soc., in press Search PubMed.
  9. M. C. Carreño, J. L. Garcia Ruano, G. Sanz, M. Toledo and A. Urbano, J. Org. Chem., 1995, 60, 5328 CrossRef CAS.
  10. M. C. Carreño, J. L. Garcia Ruano, G. Sanz, M. Toledo and A. Urbano, Tetrahdron Lett., 1996, 37, 4081 CrossRef CAS.
  11. E. B. Merkushev, N. D. Simakhina and G. M. Koveshnikova, Synthesis, 1980, 486 CrossRef CAS; Y. Ogata and K. Aoki, J. Am. Chem. Soc., 1968, 90, 6187 CrossRef CAS.
  12. D. Tzalis and Y. Tor, Chem. Commun., 1996, 1043 RSC; J. Am. Chem. Soc., 1997, 119, 852 Search PubMed.
  13. G. Balacco, J. Chem. Comput. Sci., 1994, 34, 1235 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.