Yoshihiro Sekine, Jian Chen, Naoki Eguchi and Hitoshi Miyasaka
Chem. Commun., 2020,56, 10867-10870
DOI:
10.1039/D0CC03808C,
Communication
The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann− = 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+ = tetrapropylammonium cation), by the site-doping of the Cl2Ann− bridging unit using X2Ann− units with X = Br or F.