The hierarchy and cooperativity between various non-covalent interactions within co-crystals based on a pair of aromatic carboxylic acids and 1,4-diiodoperchlorobenzene is reported.
The formation of a pair of mixed co-crystals based upon 1,4-diiodoperchlorobenzene and iodoperchlorobenzene as π-type halogen-bond donors is reported.
In this work, we have chosen Cd as the metal center to synthesize a stable 2D metal halide (C7H9N)2CdBr6 (C7H9N = 4-bromobenzylamine cation) and revealed its interesting luminescence properties through experimental studies and DFT calculations.
Four ethylene-bridged bisisoindigo-based conjugated polymers were synthesized and characterized. Combined with the more rigid backbone of (E)-1,2-di(thiophen-2-yl)ethene (DTE), PNNNN-DTE showed the highest electron mobility of 1.64 cm2 V−1 s−1.
A tetradentate host system with four C
C–Sb(C2F5)2 functions binds halide ions in a distorted square planar coordination. Experimental and calculated structures reveal a complex interplay of attractive pnictogen bonding and Coulomb repulsion.