Advancements in double decarboxylative coupling reactions of carboxylic acids

Farnaz Behmagham, Maha Mohammed Tawfiq, Mohammad Reza Poor Heravi, Nahed Mahmood Ahmed Alsultany, Suhas Ballal, Hala Bahair, A. Husein Adthab, Sattar Arshadi and Esmail Vessally

RSC Adv., 2024, 14, 14919
DOI: 10.1039/D4RA01747A

From carboxylic acids or their derivatives to amines and ethers: modern decarboxylative approaches for sustainable C–N and C–O bond formation

Weidan Yan, Tian Tian and Yasushi Nishihara

Org. Biomol. Chem., 2025, 23, 7367
DOI: 10.1039/D5OB00748H

Recent advances in light-induced direct decarboxylative halogenation catalyzed by earth-abundant metals and organic photocatalysts

Zibin Zeng, Yahao Huang, Jinglan Wen and Peng Hu

Chem. Commun., 2026
DOI: 10.1039/D5CC07425H

Facile preparation of organosilanes from benzylboronates and gem-diborylalkanes mediated by KOtBu

Man Tang, Wenyan Zhu, Huaxing Sun, Jing Wang, Su Jing, Minyan Wang, Zhuangzhi Shi and Jiefeng Hu

Chem. Sci., 2023, 14, 7355
DOI: 10.1039/D3SC02461J

C–H bond halogenation: unlocking regiodivergence and enhancing selectivity through directing group strategies

Palak Sharma, Vijay Luxami and Kamaldeep Paul

Org. Chem. Front., 2025, 12, 4066
DOI: 10.1039/D5QO00372E

Recent Development of Photoinduced Iron-Catalysis in Organic Synthesis

Qian Dou, Taimin Wang, Lijing Fang, Hongbin Zhai and Bin Cheng

Chinese Journal of Organic Chemistry, 2023, 43, 1386
DOI: 10.6023/cjoc202209001

Copper-Mediated Decarboxylative Coupling of 3-Indoleacetic Acids with Pyrazolones

Kangmei Wen, Yinrong Wu, Jiewen Chen, Jie Shi, Mulin Zheng, Xingang Yao and Xiaodong Tang

ACS Omega, 2022, 7, 5274
DOI: 10.1021/acsomega.1c06443

Electrochemical Decarboxylative Functionalizations through Carbocation Intermediates

Fei Lian, Zhoumei Tan and Kun Xu

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70137

Copper-catalyzed aerobic photodecarboxylation of carboxylic acids to aldehydes and ketones

Yonghuan Wang, Biping Xu, Xuan Xiao, Xiaoming Jie and Weiping Su

Green Synthesis and Catalysis, 2025
DOI: 10.1016/j.gresc.2025.03.006

Transition-Metal-Free Synthesis of Symmetrical 1,4-Diarylsubstituted 1,3-Diynes by Iodine-Mediated Decarboxylative Homocoupling of Arylpropiolic Acids

Subhankar Ghosh and Shital Kumar Chattopadhyay

Tetrahedron Letters, 2022, 102, 153908
DOI: 10.1016/j.tetlet.2022.153908

Decarboxylative Iodination and Suzuki-Miyaura Coupling Reactions to Access Chiral 3,3′-Diaryl-1,1′-bi-2-naphthols

Muthupandi Karthick, Sushmita Gupta and Chinnasamy Ramaraj Ramanathan

J. Org. Chem., 2024, 89, 291
DOI: 10.1021/acs.joc.3c02020

Spectroscopic and Nonlinear Optical Insights of Picolinaldehyde‐Based Materials: Experimental and DFT Approach

Ume Aiman, Muhammad Adeel, Sadia Jamal, Syeda Maria Hashmi, Wali Gul, Muhammad Atta Ur Rehman, Khurram Shahzad Munawar, Tansir Ahamad and Muhammad Haroon

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202406159

A Metal-Free Direct Decarboxylative Fluoroacylation of Indole Carboxylic Acids with Fluorinated Acids

Xingxing Zhang, Guangyuan Liu, Xing Sun, Luo-Sheng Wan and Yirong Zhou

J. Org. Chem., 2024, 89, 14591
DOI: 10.1021/acs.joc.4c01842

Photoinduced ligand-to-copper charge transfer for decarboxylative hydrogenation of aromatic carboxylic acids

Zhengjia Shen, Jiani Wei, Xue Hu, Zimu Gu, Qiqi Shao, Xuan Chen, Mingming Wang and Dongliang Zhang

Tetrahedron, 2025, 175, 134536
DOI: 10.1016/j.tet.2025.134536

Photoinduced Ligand-to-Copper Charge Transfer for Aryl Decarboxylative Allylation, Thiolation, and Bromination

Ao-Men Hu, Jia-Lin Tu, Ke Wang, Jiawen Yin, Lin Guo, Chao Yang and Wujiong Xia

Org. Lett., 2024, 26, 8572
DOI: 10.1021/acs.orglett.4c03188

Light‐Induced Direct Decarboxylative Functionalization of Aromatic Carboxylic Acids

Jia‐Lin Tu, Zhengjia Shen and Binbin Huang

Adv Synth Catal, 2024, 366, 4263
DOI: 10.1002/adsc.202400573

Recent Metal-Catalyzed Methods for Thioether Synthesis

Valentin J. Geiger, Regina M. Oechsner, Paul H. Gehrtz and Ivana Fleischer

Synthesis, 2022, 54, 5139
DOI: 10.1055/a-1914-1231

Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals

Jihong Lan, Rongxiang Chen, Fangfang Duo, Menghui Hu and Xiaoyan Lu

Molecules, 2022, 27, 5364
DOI: 10.3390/molecules27175364

Air-triggered, catalyst-free decarboxylative oxysulfonylation of arylpropiolic acids with sodium sulfinates

Xingyu Chen, Xiaoqiang Chang, Shuaichen Zhang, Sixian Lu, Lan Yang and Peng Sun

Environ Chem Lett, 2022, 20, 2773
DOI: 10.1007/s10311-022-01440-x

Palladium-Catalyzed Double Decarboxylative [3 + 2] Annulation of Naphthalic Anhydrides with Internal Alkynes

Chaipot Kanganavaree, Kritchasorn Kantarod, Thanapat Worakul, Darunee Soorukram, Chutima Kuhakarn, Khetpakorn Chakarawet, Worawat Wattanathana, Panida Surawatanawong, Vichai Reutrakul and Pawaret Leowanawat

J. Org. Chem., 2024, 89, 15083
DOI: 10.1021/acs.joc.4c01747

Field Effects Govern the Decarboxylation of Copper(II)-Benzoates: Kinetic and Mechanistic Studies

Shannen C. Lorraine, Andreas Baur, Natalie Taylor, Brian S. Dolinar and Jessica M. Hoover

Organometallics, 2026, 45, 169
DOI: 10.1021/acs.organomet.5c00415

Radical‐Mediated C−H Alkylation of Glycine Derivatives: A Straightforward Strategy for Diverse α‐Unnatural Amino Acids

Madala Hari Babu and Jaehoon Sim

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200859

A Facile Procedure for Halodecarboxylation of Hydroxyaromatic Carboxylic Acids

Zhenbei Zhang, Wenhui Sun, Zhishan Cao, Guisheng Zhang, Olha Bakumenko and Feng Xue

Synlett, 2024, 35, 2117
DOI: 10.1055/a-2294-4029

Electrooxidative Ni‐Catalyzed Decarboxylation of Arylacetic Acids Towards the Synthesis of Carbonyls under Air Conditions

Zhengjiang Fu, Junhua Zeng, Cheng Xiong, Shengmei Guo and Hu Cai

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202403077

Phosphine-mediated deoxygenative synthesis of amides from carboxylic acids and N-chloro compounds

Jiahong Chen, Hanjing Deng, Pengyu Zhang and You Zi

Tetrahedron Letters, 2025, 171-172, 155813
DOI: 10.1016/j.tetlet.2025.155813

Decarboxylative bromination and chlorination of carboxylate salts: from discovery (Alexander Borodin, 1861) to development of a synthetic methodology (Cläre and Heinz Hunsdiecker, 1935–1942) and present perspectives of the reaction

Enzo Santaniello and Jelena Lazarević

Chem. Pap., 2025, 79, 4807
DOI: 10.1007/s11696-025-04077-6